Photochemically-Induced N-N Bond Cleavage of N,N-Disubstituted Hydrazides

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ECSOC-13 | General Organic Synthesis

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13th Int. Electron. Conf. Synth. Org. Chem. 2009, a008:1-4

Communication

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Photochemically-Induced N-N Bond Cleavage of N,N-Disubstituted Hydrazides

Stéphane Lebrun, Axel Couture*

, Éric Deniau and Pierre Grandclaudon

UMR CNRS 8009 "Chimie Organique et Macromoléculaire", Université des Sciences et Technologies de Lille 1, Laboratoire de Chimie Organique Physique, Bâtiment C3(2), F-59655 Villeneuve d'Ascq Cedex, France; * Author to whom correspondence should be addressed.

(This article belongs to the section A. General Organic Synthesis)

Cite this paper as: Lebrun, S.; Couture, A.; Deniau, �.; Grandclaudon, P. Photochemically-Induced N-N Bond Cleavage of N,N-Disubstituted Hydrazides. In Proceedings of the 13th Int. Electron. Conf. Synth. Org. Chem., 1-30 November 2009; Sciforum Electronic Conferences Series, 2009, a008:1-4.

Abstract: The development of an unprecedented methodology based upon direct photolysis of N,N-disubstituted hydrazides to secure N-N bond cleavage and to trigger off the formation of NH free lactams has been disclosed.

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