METHYLENE INSERTION IN VINYLCUPRATES BEARING AN ALLYLIC SILYL GROUP

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13th Int. Electron. Conf. Synth. Org. Chem. 2009, a025:1-4

Communication

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METHYLENE INSERTION IN VINYLCUPRATES BEARING AN ALLYLIC SILYL GROUP

Francisco Pulido*, Asunción Barbero*, Raquel Abad, Alberto Diez de la Varga, Sergio Ferrero, Patricia Val, Alfonso González and Carmen Sañudo

Departamento de Química Orgánica, Universidad de Valladolid, 47011 Valladolid, Spain; * Author to whom correspondence should be addressed.

(This article belongs to the section A. General Organic Synthesis)

Cite this paper as: Pulido, F.; Barbero, A.; Abad, R.; Diez de la Varga, A.; Ferrero, S.; Val, P.; González, A.; Sañudo, C. METHYLENE INSERTION IN VINYLCUPRATES BEARING AN ALLYLIC SILYL GROUP. In Proceedings of the 13th Int. Electron. Conf. Synth. Org. Chem., 1-30 November 2009; Sciforum Electronic Conferences Series, 2009, a025:1-4.

Abstract: The silylcupration of allene has emerged as a useful tool for the synthesis of functionalized allylsilanes which have been used in the synthesis of different-sized carbocycles. We now described the preparation of allylsilane-allylcuprate intermediates by homologation reaction with iodomethylzinc iodide and their reaction with different electrophiles.

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